The thioether group: A good substitute for oxidative fluorination

被引：13

作者：

Laurent, E ^{[1
]}

Marquet, B ^{[1
]}

Roze, C ^{[1
]}

Ventalon, F ^{[1
]}

机构：

[1] UCB Lyon 1, Lab Chim Organ 3, CNRS, F-69622 Villeurbanne, France

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1998年 / 87卷 / 02期

关键词：

fluorination; electrofluorination; oxidation; alpha-fluoroesters; alpha-fluorothioethers; alpha-thioesters; alpha-thioacids;

D O I：

10.1016/S0022-1139(97)00148-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Regiospecific monofluorinations of alpha-thio alpha-arylesters and alpha-thioacids were obtained by anodic and/or chemical oxidation in fluorinating media. This procedure provided a convenient synthesis of alpha-fluoroesters via the CS bond cleavage induced by anodic process while chemical or electrochemical oxidation of alpha-thioacids underwent a fluoro decarboxylation, affording alpha-fluorothioethers. (C) 1998 Elsevier Science S.A.

引用

页码：215 / 220

页数：6

共 24 条

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