Enhanced selectivity in the conversion of methanol to 2,2,3-trimethylbutane (triptane) over zinc iodide by added phosphorous or hypophosphorous acid

被引：18

作者：

Bercaw, John E. ^{[1
]}

Grubbs, Robert H. ^{[1
]}

Hazari, Nilay ^{[1
]}

Labinger, Jay A. ^{[1
]}

Li, Xingwei ^{[1
]}

机构：

[1] CALTECH, Arnold & Mabel Beckman Labs Chem Synth, Pasadena, CA 91125 USA

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 28期

关键词：

D O I：

10.1039/b705470j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The yield of triptane from the reaction of methanol with zinc iodide is dramatically increased by addition of phosphorous or hypophosphorous acid, via transfer of hydride from a P-H bond to carbocationic intermediates.

引用

页码：2974 / 2976

页数：3

共 10 条

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