Recent developments in palladium-catalyzed oxidations

被引：14

作者：

Backvall, JE

机构：

[1] Department of Organic Chemistry, University of Uppsala, S-751 21 Uppsala

来源：

PURE AND APPLIED CHEMISTRY | 1996年 / 68卷 / 03期

关键词：

D O I：

10.1351/pac199668030535

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The palladium-catalyzed intramolecular 1,4-oxidation of conjugated dienes has been extended to carbon-carbon bond formation. Two different methods were developed. In the first method, a vinylpalladium intermediate is generated in the side chain which adds to the diene. In the other method an allylsilane is used as nucleophile in the side chain. The first type of reaction leads to a 1,4-anti addition of carbon and a chloride and the second to a 1,4-syn addition of carbon and chloride to the 1,3-diene.

引用

页码：535 / 538

页数：4

共 13 条

[1]

BACKVALL JE, 1990, J AM CHEM SOC, V112, P3683

[2]

BACKVALL JE, 1993, J ORG CHEM, V58, P5445

[3]

BACKVALL JE, 1992, J AM CHEM SOC, V114, P6374

[4]

BACKVALL JE, 1985, J AM CHEM SOC, V107, P3676

[5]

BACKVALL JE, 1984, J ORG CHEM, V49, P4619

[6] CARBON-CARBON BOND FORMATION IN PALLADIUM(II)-CATALYZED INTRAMOLECULAR 1,4-OXIDATION OF CONJUGATED DIENES [J].

BACKVALL, JE ;

NILSSON, YIM ;

ANDERSSON, PG ;

GATTI, RGP ;

WU, JC .

TETRAHEDRON LETTERS, 1994, 35 (31) :5713-5716

[7] PALLADIUM-CATALYZED INTRAMOLECULAR 1,4-ADDITIONS TO CONJUGATED DIENES [J].

BACKVALL, JE .

PURE AND APPLIED CHEMISTRY, 1992, 64 (03) :429-437

[8]

BACKVALL JE, ADV METAL ORGANIC CH

[9]

CASTANO A, IN PRESS J AM CHEM S

[10]

CASTANO AR, UNPUB

← 1 2 →