Unexpected synthesis of an 8-shaped macrocycle instead of an interlocking-ring system

被引：51

作者：

Belfrekh, N ^{[1
]}

Dietrich-Buchecker, C ^{[1
]}

Sauvage, JP ^{[1
]}

机构：

[1] Univ Strasbourg 1, Inst Le Bel, CNRS,UMR 7513, Lab Chim Organo Mineral, F-67070 Strasbourg, France

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 22期

关键词：

D O I：

10.1021/ic991502k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An iron(II)-bis(terpyridine) core is used as a template to synthesize a 58-membered ring in good yield, instead of the expected corresponding interlocking-ring system. The X-ray structure of the iron complex shows the ring to be twisted and to display an 8-shaped geometry.

引用

页码：5169 / 5172

页数：4

共 16 条

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