Radical-initiated, skeletal rearrangements of bicyclo[2.2.2] lactones

被引：32

作者：

Markó, IE ^{[1
]}

Warriner, SL ^{[1
]}

Augustyns, B ^{[1
]}

机构：

[1] Univ Catholique Louvain, Dept Chim, B-1348 Louvain, Belgium

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 20期

关键词：

D O I：

10.1021/ol006324+

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Treatment of bicyclic lactones derived from Diels-Alder reactions of 3-carbomethoxy-2-pyrone under radical conditions leads to a series of interesting skeletal rearrangements. The stereochemical and optical integrity of the starting material are maintained throughout the process.

引用

页码：3123 / 3125

页数：3

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