Total asymmetric synthesis of (7S,9R)-(+)-bisacumol

被引：29

作者：

Li, AP

Yue, GR

Li, Y

Pan, XF ^{[1
]}

Yang, TK

机构：

[1] Lanzhou Univ, Dept Chem, Natl Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

[2] Natl Chung Hsing Univ, Dept Chem, Taichung 40227, Taiwan

来源：

TETRAHEDRON-ASYMMETRY | 2003年 / 14卷 / 01期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/S0957-4166(02)00759-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

A facile stereoselective synthetic route to (7S,9R)-(+)-bisacumol 1 has been achieved. This novel approach derives its asymmetry by employing asymmetric dihydroxylation and CBS reduction processes. The resulting sesquiterpene 1 was produced with highly enantio- and diastereoselectivity. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：75 / 78

页数：4

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