Selective formation of pentan-3-one from carbon monoxide and ethene in methanol

被引：9

作者：

Robertson, RAM

Poole, AD

Payne, MJ

Cole-Hamilton, DJ ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[2] BP Amoco Chem, Hull HU12 8DS, N Humberside, England

[3] BP Amoco Chem, Sunbury Res Ctr, Sunbury TW16 7LN, Middx, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 12期

关键词：

D O I：

10.1039/b002629h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the presence of rhodium complexes of triethylphosphine, CO and ethene react in methanol to give pentan-3-one with selectivities up to 85%; model studies and deuterium labelling suggest that the mechanism involves hydroxycarbene and eta(2)-3-oxopentyl derivatives.

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页码：1817 / 1819

页数：3

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