A new precursor to electroconducting conjugated polymers: Synthesis and opto-electrical properties of luminescent devices based on these PPV derivatives

被引：8

作者：

Bijnens, W ^{[1
]}

Van Der Borght, M ^{[1
]}

Manca, J ^{[1
]}

De Ceuninck, W ^{[1
]}

De Schepper, L ^{[1
]}

Vanderzande, D ^{[1
]}

Gelan, J ^{[1
]}

Stals, L ^{[1
]}

机构：

[1] Limburgs Univ Ctr, Inst Mat Onderzoek, B-3590 Diepenbeek, Belgium

来源：

OPTICAL MATERIALS | 1998年 / 9卷 / 1-4期

关键词：

D O I：

10.1016/S0925-3467(97)00084-0

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A variety of novel conjugated PPV-related polymers have been synthesised using a synthetic approach that allows the tailoring of the chemical structure of the polymer backbone. In this way we have been able to prepare not only poly(p-phenylene vinylene) (PPV) (1), but also some electron-rich PPV derivatives such as poly(2,5-dimethyl-1,4-phenylene vinylene) (PDMetPV) (2) and poly(2,5-dimethoxy-1,4-phenylene vinylene) (PDMeoPV) (3) and PPV derivatives with an enlarged aromatic system, poly(4,4'-bisphenylene vinylene) (PBPV) (4) and poly(2,6-naphtalene vinylene) (PNV) (5). These materials were characterised in terms of molecular weight (GPC), elimination temperature (TGA, FT-IR), optical properties (UV-VIS), photoluminescence (PL) and device characteristics of the LEDs. (C) 1998 Elsevier Science B.V.

引用

页码：150 / 153

页数：4

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