Time-stress correspondence in viscoelastic materials: an equation for the stress and temperature shift factor

被引:54
作者
Brostow, W [1 ]
机构
[1] Univ N Texas, Dept Mat Sci, Lab Polymers & Composites, LAPOM, Denton, TX 76203 USA
[2] Univ N Texas, Dept Chem, Lab Polymers & Composites, LAPOM, Denton, TX 76203 USA
关键词
viscoelasticity; temperature shift factor; stress shift factor; polymer property prediction; polymer reliability; polymer mechanical properties; time-stress correspondence; time-temperature correspondence; thermal mechanical analysis; equation of state; Hartmann equation; creep compliance;
D O I
10.1007/s100190000054
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Stress-time correspondence principle discovered experimentally by O'Shaughnessy already in 1948 [1] is considered. Using the Doolittle formula for the viscosity as a function of free volume 12], an equation for the generalized temperature-stress shift factor a(T,sigma) is obtained. An equation for the stress-dependent shift factor a(sigma) follows as a special case. The equation for the temperature shift factor a(T) already derived in 1985 [3] and successfully used since also follows from the a(T,sigma) formula.
引用
收藏
页码:347 / 351
页数:5
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