Length-dependent band-gap shift of TiO32- molecular wires embedded in zeolite ETS-10

被引：38

作者：

Jeong, Nak Cheon

Lee, Myoung Hee

Yoon, Kyung Byung ^{[1
]}

机构：

[1] Sogang Univ, Dept Chem, Ctr Microcrystal Assembly, Ctr Nanoporous Mat, Seoul 121742, South Korea

[2] Sogang Univ, Dept Chem, Program Integrated Biotechnol, Seoul 121742, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 31期

关键词：

electronic properties; molecular wires; zeolites;

D O I：

10.1002/anie.200701676

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Mind the gap! The titanosilicate zeolite ETS-10 contains TiO32- molecular wires (see picture). A reliable method has been developed to synthesize high-quality ETS-10 crystals of various sizes. Measurements on the crystals allow the dependence of the band-gap energy on the length of the TiO32- wires to be elucidated. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

收藏

页码：5868 / 5872

页数：5

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