On-line detection for supercritical-fluid extraction

被引：15

作者：

Amador-Hernández, J ^{[1
]}

De Castro, MDL ^{[1
]}

机构：

[1] Univ Cordoba, Fac Sci, Dept Analyt Chem, E-14004 Cordoba, Spain

来源：

JOURNAL OF BIOCHEMICAL AND BIOPHYSICAL METHODS | 2000年 / 43卷 / 1-3期

关键词：

supercritical-fluid extraction; on-line detection; automation;

D O I：

10.1016/S0165-022X(00)00097-X

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

An overview of the direct coupling of supercritical-fluid extraction (SFE) to distinct detection is presented. The versatile construction of this kind of hybrid analytical instrumentation is manifested through the discussion of several interface prototypes, whose characteristics satisfy the requirements of both the SF extractor and detector. The application of several experimental strategies during the whole analytical process are proposed for the successful quantification of the leaching yield. Typical examples of SFE with on-line detection in several fields of analysis are presented, considering of special interest the information provided by the molecular and atomic techniques used. Finally, the real analytical capabilities of the automation of sample handling by SFE-continuous detection are also discussed. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：329 / 343

页数：15

共 29 条

[1] Near infrared thermal lens spectrometry for the real-time monitoring of supercritical fluid extraction [J].

Amador-Hernández, J ;

Fernández-Romero, JM ;

de Castro, MDL .

TALANTA, 1999, 49 (04) :813-823

[2] Monitoring supercritical fluid extraction by thermal lens spectrometry with pulsed laser excitation [J].

Amador-Hernández, J ;

Fernández-Romero, JM ;

Ramis-Ramos, G ;

de Castro, MDL .

ANALYTICA CHIMICA ACTA, 1999, 390 (1-3) :163-173

[3] ON LINE MONITORING OF THE SUPERCRITICAL-FLUID EXTRACTION PROCESS WITH PROTON NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY [J].

BRAUMANN, U ;

HANDEL, H ;

ALBERT, K ;

ECKER, R ;

SPRAUL, M .

ANALYTICAL CHEMISTRY, 1995, 67 (05) :930-935

[4] MEMBRANE INTERFACE FOR ONLINE SUPERCRITICAL-FLUID EXTRACTION FLOW-INJECTION ANALYSIS [J].

BREWSTER, JD ;

MAXWELL, RJ ;

HAMPSON, JW .

ANALYTICAL CHEMISTRY, 1993, 65 (15) :2137-2140

[5] OPTIMIZATION OF ARSENIC SUPERCRITICAL-FLUID EXTRACTION WITH DETECTION BY INDUCTIVELY-COUPLED PLASMA-MASS SPECTROMETRY [J].

CLELAND, SL ;

OLSON, LK ;

CARUSO, JA ;

CAREY, JM .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1994, 9 (09) :975-979

[6] Determination of total petroleum hydrocarbons in soil by on-line supercritical fluid extraction infrared spectroscopy using a fiberoptic transmission cell and a simple filter spectrometer [J].

Current, RW ;

Tilotta, DC .

JOURNAL OF CHROMATOGRAPHY A, 1997, 785 (1-2) :269-277

[7]

De Castro M. D. L., 1994, ANAL SUPERCRITICAL F

[8] CARBON-DIOXIDE SUPERCRITICAL-FLUID EXTRACTION WITH ONLINE FLUORESCENCE DETECTION [J].

DUNHAM, DC ;

DESMARAIS, MS ;

BREID, T ;

HILLS, JW .

ANALYTICAL LETTERS, 1995, 28 (14) :2561-2574

[9] SIMPLE FIBEROPTIC INTERFACE FOR ONLINE SUPERCRITICAL-FLUID EXTRACTION FOURIER-TRANSFORM INFRARED SPECTROMETRY [J].

HEGLUND, DL ;

TILOTTA, DC ;

HAWTHORNE, SB ;

MILLER, DJ .

ANALYTICAL CHEMISTRY, 1994, 66 (20) :3543-3551

[10] SUPERCRITICAL FLUID EXTRACTION AND DIRECT FLUID INJECTION MASS-SPECTROMETRY FOR THE DETERMINATION OF TRICHOTHECENE MYCOTOXINS IN WHEAT SAMPLES [J].

KALINOSKI, HT ;

UDSETH, HR ;

WRIGHT, BW ;

SMITH, RD .

ANALYTICAL CHEMISTRY, 1986, 58 (12) :2421-2425

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