The influence of alumina on the performance of FCC catalysts during hydrotreated VGO catalytic cracking

被引:31
作者
Al-Khattaf, S [1 ]
机构
[1] King Fahd Univ Petr & Minerals, Dept Chem Engn, Dhahran 31261, Saudi Arabia
关键词
D O I
10.1021/ef020066a
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Two categories of FCC catalysts were prepared. The first one is an FCC catalyst containing Y-zeolite and amorphous matrix. The second category is amorphous catalyst without Y-zeolite. Alumina was systematically added to both catalyst categories, The addition of alumina to the FCC catalyst containing Y-zeolite forms an active matrix. The inactive matrix of the catalyst is composed of kaolin filler and silica sol binder. The experimental data clearly show that alumina addition to both catalyst categories substantially increased both catalyst surface area and acidity, The addition of alumina to the amorphous catalyst resulted in a significant increase in hydrotreated VGO conversion. However, similar alumina addition to Y-zeolite containing catalysts did not appear to have a significant effect on the hydrotreated VGO conversion.
引用
收藏
页码:62 / 68
页数:7
相关论文
共 21 条
[1]   Activity and selectivity of fluidized catalytic cracking catalysts in a riser simulator: The role of Y-zeolite crystal size [J].
Al-Khattaf, S ;
de Lasa, H .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1999, 38 (04) :1350-1356
[2]   The role of diffusion in alkyl-benzenes catalytic cracking [J].
Al-Khattaf, S ;
de Lasa, H .
APPLIED CATALYSIS A-GENERAL, 2002, 226 (1-2) :139-153
[3]   The influence of Y-zeolite unit cell size on the performance of FCC catalysts during gas oil catalytic cracking [J].
Al-Khattaf, S .
APPLIED CATALYSIS A-GENERAL, 2002, 231 (1-2) :293-306
[4]  
ALKHATTAF S, 2001, CAN J CHEM ENG, V3, P79
[5]  
Andersson SI, 1997, OIL GAS-EUR MAG, V23, P19
[6]   INFLUENCE OF FRAMEWORK ALUMINUM GRADIENTS ON THE CATALYTIC ACTIVITY OF Y-ZEOLITES - CRACKING OF GAS-OIL ON Y-ZEOLITES DEALUMINATED BY DIFFERENT PROCEDURES [J].
ARRIBAS, J ;
CORMA, A ;
FORNES, V ;
MELO, F .
JOURNAL OF CATALYSIS, 1987, 108 (01) :135-142
[7]  
DEJONG J, KETJ CAT S 1986 SCHE
[8]  
HUMPHRIES A, 1989, OIL GAS J 0206
[9]  
HUMPHRIES D, 1993, FLUID CATALYTIC CRAC, P41
[10]   Effect of unit cell size on the activity and coke selectivity of FCC catalysts [J].
Ino, T ;
AlKhattaf, S .
APPLIED CATALYSIS A-GENERAL, 1996, 142 (01) :5-17