Fluorescence patterning through photoinduced migration of squaraine-functionalized azo derivatives

被引:51
作者
Liu, Li-Hong
Nakatani, Keitaro
Pansu, Robert
Vachon, Jean-Jacques
Tauc, Patrick
Ishow, Elena
机构
[1] ENS, CNRS, PPSM, UMR 8531, F-94235 Cachan, France
[2] ENS, CNRS, UMR 8113, LBPA, F-94235 Cachan, France
关键词
D O I
10.1002/adma.200601695
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
New photochromic and fluorescent dyes are formed by covalently attaching emissive squaraine units to azo moieties. Illumination of doped matrices by light interference fringes provokes the reversible migration of the dyes and the formation of fluorescent gratings, as shown schematically in the figure. The visualization of the gratings is performed by using fluorescence confocal microscopy.
引用
收藏
页码:433 / +
页数:5
相关论文
共 18 条
[1]   1H NMR spectral evidence for a specific host-guest complexation induced charge localization in squaraine dyes [J].
Ajayaghosh, A ;
Arunkumar, E .
ORGANIC LETTERS, 2005, 7 (15) :3135-3138
[2]   Chemistry of squaraine-derived materials: Near-IR dyes, low band gap systems, and cation sensors [J].
Ajayaghosh, A .
ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (06) :449-459
[3]   Proton controlled intramolecular photoinduced electron transfer (PET) in podand linked squaraine-aniline dyads [J].
Arunkumar, E ;
Ajayaghosh, A .
CHEMICAL COMMUNICATIONS, 2005, (05) :599-601
[4]   A squaraine-based chemosensor for Hg2+ and Pb2+ [J].
Basheer, MC ;
Alex, S ;
Thomas, KG ;
Suresh, CH ;
Das, S .
TETRAHEDRON, 2006, 62 (04) :605-610
[5]   Aggregation of surfactant squaraine dyes in aqueous solution and microheterogeneous media: Correlation of aggregation behavior with molecular structure [J].
Chen, HJ ;
Farahat, MS ;
Law, KY ;
Whitten, DG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (11) :2584-2594
[6]   Molecular migration mechanism for laser induced surface relief grating formation [J].
Fiorini, C ;
Prudhomme, N ;
de Veyrac, G ;
Maurin, I ;
Raimond, P ;
Nunzi, JM .
SYNTHETIC METALS, 2000, 115 (1-3) :121-125
[7]  
Knoll, 2002, PHOTOREACTIVE ORGANI, P429
[8]   Chromophore orientations in surface relief gratings with second-order nonlinearity as studied by confocal polarized Raman microspectrometry [J].
Lagugné-Labarthet, F ;
Bruneel, JL ;
Rodriguez, V ;
Sourisseau, C .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (04) :1267-1278
[9]  
LAGUGNELABARTHE.F, 2004, J PHYS CHEM B, V108, P6949
[10]   SQUARAINE CHEMISTRY - EFFECTS OF SOLVENT AND TEMPERATURE ON THE FLUORESCENCE EMISSION OF SQUARAINES [J].
LAW, KY .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1994, 84 (02) :123-132