Chemical fixation of carbon dioxide to styrene carbonate under supercritical conditions with DMF in the absence of any additional catalysts

被引：177

作者：

Kawanami, H

Ikushima, Y

机构：

[1] Natl Ind Res Inst Tohoku, Miyagino Ku, Sendai, Miyagi 9838551, Japan

[2] Japan Sci & Technol Corp, JST, CREST, Tokyo 1028666, Japan

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 21期

关键词：

D O I：

10.1039/b006682f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chemical fixation of carbon dioxide to styrene carbonate proceeds effectively under supercritical conditions with DMF even in the absence of any additional catalysts, giving a maximum yield of 85% in the near-critical region.

引用

页码：2089 / 2090

页数：2

共 15 条

[1] Multiphase catalysis using water-soluble metal complexes in supercritical carbon dioxide [J].

Bhanage, BM ;

Ikushima, Y ;

Shirai, M ;

Arai, M .

CHEMICAL COMMUNICATIONS, 1999, (14) :1277-1278

[2] Heck reactions using water-soluble metal complexes in supercritical carbon dioxide [J].

Bhanage, BM ;

Ikushima, Y ;

Shirai, M ;

Arai, M .

TETRAHEDRON LETTERS, 1999, 40 (35) :6427-6430

[3] Reaction of dialkyltin methoxide with carbon dioxide relevant to the mechanism of catalytic carbonate synthesis [J].

Choi, JC ;

Sakakura, T ;

Sako, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (15) :3793-3794

[4] SUPERCRITICAL CARBON-DIOXIDE AS SOLVENT FOR THE COPOLYMERIZATION OF CARBON-DIOXIDE AND PROPYLENE-OXIDE USING A HETEROGENEOUS ZINC CARBOXYLATE CATALYST [J].

DARENSBOURG, DJ ;

STAFFORD, NW ;

KATSURAO, T .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 104 (01) :L1-L4

[5] PRESSURE EFFECT ON THE ESTERIFICATION OF PHTHALIC-ANHYDRIDE IN SUPERCRITICAL CO2 [J].

ELLINGTON, JB ;

BRENNECKE, JF .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (13) :1094-1095

[6] ACTIVATION OF A LIPASE TRIGGERED BY INTERACTIONS WITH SUPERCRITICAL CARBON-DIOXIDE IN THE NEAR-CRITICAL REGION [J].

IKUSHIMA, Y ;

SAITO, N ;

ARAI, M ;

BLANCH, HW .

JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (22) :8941-8944

[7]

IKUSHIMA Y, 1999, CHEM SYNTHESIS USING

[8]

JESSOP PG, 1994, NATURE, V368, P687

[9] CATALYTIC ACTIVITY OF VARIOUS SALTS IN THE REACTION OF 2,3-EPOXYPROPYL PHENYL ETHER AND CARBON-DIOXIDE UNDER ATMOSPHERIC-PRESSURE [J].

KIHARA, N ;

HARA, N ;

ENDO, T .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (23) :6198-6202

[10] CLUSTERING IN SUPERCRITICAL FLUID MIXTURES [J].

KIM, SW ;

JOHNSTON, KP .

AICHE JOURNAL, 1987, 33 (10) :1603-1611

← 1 2 →