Design, synthesis and structural studies on polynucleating ligands based on atropoisomerism of catechol bearing porphyrins

被引：16

作者：

Drexler, C

Hosseini, MW

Planeix, JM

Stupka, G

De Cian, A

Fischer, J

机构：

[1] Univ Strasbourg 1, CNRS, UMR 7513, Chim Coordinat Organ Lab, F-67000 Strasbourg, France

[2] Univ Strasbourg 1, UMR 7513, Lab Cristallochim & Chim Struct, F-67000 Strasbourg, France

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 06期

关键词：

D O I：

10.1039/a707949d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High yield syntheses of all four atropoisomers of the mesotetrakis(o-catecholamidophenyl)porphyrin has been achieved; all four atropoisomers were isolated and characterised by NMR spectroscopy; for the methyl protected 2(alpha beta alpha beta) and 2(alpha 4) atropoisomers obtained as water and chloroform solvates respectively, X-ray analysis was used to assign their structure.

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页码：689 / 690

页数：2

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