Solvent-free liquid phase oxidation of benzyl alcohol to benzaldehyde by molecular oxygen using non-noble transition metal containing hydrotalcite-like solid catalysts

被引：214

作者：

Choudhary, VR ^{[1
]}

Chaudhari, PA ^{[1
]}

Narkhede, VS ^{[1
]}

机构：

[1] Natl Chem Lab, Div Chem Engn, Pune 411008, Maharashtra, India

来源：

CATALYSIS COMMUNICATIONS | 2003年 / 4卷 / 04期

关键词：

oxidation of benzyl alcohol to benzaldehyde; transition metal containing hydrotalcite-like catalysts; solvent-free oxidation of benzyl alcohol;

D O I：

10.1016/S1566-7367(03)00027-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Performance of Co-Al, Ni-Al, Cu-Al, Zn-Cu-Al, Mg-Fe, Co-Fe, Ni-Fe, Mn-Cr, Co-cr, Ni-cr, Zn-Cr and Cu-Cr hydrotalcite-like solid catalysts has been evaluated for the liquid phase oxidation of benzyl alcohol to benzaldehyde using molecular oxygen as an oxidizing agent in the absence of any solvent. The Mn and Cu containing hydrotalcite-like solids show good catalytic activity in the oxidation and hence these are promising catalysts for the solvent-free oxidation reaction.. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：171 / 175

页数：5

共 17 条

[1] Effect of alkali-metal promoter on silica-supported copper catalysts in benzyl alcohol oxidation
Arai, M
Nishiyama, S
Tsuruya, S
Masai, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (14): : 2631 - 2636
[2] BIJLANI NS, 1981, INDIAN CHEM ENG, V23, P44
[3] Choudary BM, 2001, ANGEW CHEM INT EDIT, V40, P763, DOI 10.1002/1521-3773(20010216)40:4<763::AID-ANIE7630>3.0.CO
[4] 2-T
[5] Solvent-free selective oxidation of benzyl alcohol and benzaldehyde by tert-butyl hydroperoxide using MnO4--exchanged Mg-Al-hydrotalcite catalysts
Choudhary, VR
Dumbre, DK
Narkhede, VS
Jana, SK
[J]. CATALYSIS LETTERS, 2003, 86 (04) : 229 - 233
[6] THE EFFECT OF ALKALI PROMOTERS ON CU-NA-ZSM-5 CATALYSTS IN THE OXIDATION OF BENZYL ALCOHOL
HAYASHIBARA, H
NISHIYAMA, S
TSURUYA, S
MASAI, M
[J]. JOURNAL OF CATALYSIS, 1995, 153 (02) : 254 - 264
[7] Role of potassium added to Ce/NaZSM-5 catalyst in partial oxidation activity of benzyl alcohol
Idaka, N
Nishiyama, S
Tsuruya, S
[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2001, 3 (10) : 1918 - 1924
[8] Kroschwitz J.I., 1992, KIRK OTHMER ENCY CHE, V4, P64
[9] Liquid phase selective oxidation of benzyl alcohol over Pd-Ag catalysts supported on pumice
Liotta, LF
Venezia, AM
Deganello, G
Longo, A
Martorana, A
Schay, Z
Guczi, L
[J]. CATALYSIS TODAY, 2001, 66 (2-4) : 271 - 276
[10] New Gallium-Substituted Hydrotaleites: [Mg1-xGax(OH)2](CO3)x/2 • mH2O
Lopez-Salinas, Esteban
Garcia-Sanchez, Mayela
Luisa Ramon-Garcia, Ma.
Schifter, Isaac
[J]. JOURNAL OF POROUS MATERIALS, 1996, 3 (03) : 169 - 174

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