Oxidation of fullerenes by ozone

被引：10

作者：

Deng, JP

Mou, CY

Han, CC

机构：

[1] Natl Taiwan Univ, Dept Chem, Taipei 10764, Taiwan

[2] Acad Sinica, Inst Atom & Mol Sci, Taipei, Taiwan

来源：

FULLERENE SCIENCE AND TECHNOLOGY | 1997年 / 5卷 / 07期

关键词：

D O I：

10.1080/15363839708013323

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Like typical alkenes, fullerenes can be oxidized by ozone. Epoxidation reaction takes place on C-60, and C(60)On (n=1-5) are formed. Mass spectrometry and chromotography identified the stable existence of two isomers for the dioxides and three for the trioxides in the product mixtures. At lower temperatures, fragmentation occurs and results in the formation of the polar products. C-70 and carbon nanotubes also react with ozone but at a much slower rate.

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收藏

页码：1325 / 1336

页数：12

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