学术探索
学术期刊
新闻热点
数据分析
智能评审

TRISPHAT-N:: A chiral hexacoordinated phosphate anion with unique asymmetric coordinating properties

被引：18
作者：
Constant, Samuel
Frantz, Richard
Mueller, Jessica
Bernardinelli, Gerald
Lacour, Jerome
机构：
[1] Univ Geneva, Dept Chim Organ, CH-1211 Geneva 4, Switzerland
[2] Univ Geneva, Crystallog Lab, CH-1211 Geneva 4, Switzerland
来源：
ORGANOMETALLICS | 2007年 / 26卷 / 09期
关键词：
D O I：
10.1021/om070074k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A simple and efficient chiral anionic N-ligand: the introduction of a Lewis basic nitrogen onto the TRISPHAT skeleton allows the direct and efficient stereocontrol of tropos chiral ligands bound to metal complexes or of stereogenic metal centers (dr up to 96:4).
引用
收藏
页码：2141 / 2143
页数：3
相关论文
共 44 条
  • [1] Vibrational and electronic circular dichroism of Δ-TRISPHAT [tris(tetrachlorobenzenediolato)-phosphate(V)] anion
    Bas, D
    Bürgi, T
    Lacour, J
    Vachon, J
    Weber, J
    [J]. CHIRALITY, 2005, 17 : S143 - S148
  • [2] Effective chiral recognition among ions in polar media
    Bergman, SD
    Frantz, R
    Gut, D
    Kol, M
    Lacour, J
    [J]. CHEMICAL COMMUNICATIONS, 2006, (08) : 850 - 852
  • [3] Neutral metallomacrocycles with four or ten (PEt3)Pd(II) centers
    Brasey, T
    Scopelliti, R
    Severin, K
    [J]. INORGANIC CHEMISTRY, 2005, 44 (02) : 160 - 162
  • [4] Optically active transition metal complexes. 129. Novel cycloheptatrienyl-molybdenum and cyclopentadienyl-ruthenium complexes with chiral pyridinecarbaldiminato chelate ligands: Syntheses, molecular structures, properties, and stereochemistry at the metal atom
    Brunner, H
    Klankermayer, J
    Zabel, M
    [J]. ORGANOMETALLICS, 2002, 21 (26) : 5746 - 5756
  • [5] Brunner H, 1999, ANGEW CHEM INT EDIT, V38, P1195, DOI 10.1002/(SICI)1521-3773(19990503)38:9<1194::AID-ANIE1194>3.0.CO
  • [6] 2-X
  • [7] Brunner H, 2001, EUR J INORG CHEM, P905
  • [8] A comparison of the lability of mononuclear octahedral and dinuclear triple-helical complexes of cobalt(II)
    Charbonniere, LJ
    Williams, AF
    Frey, U
    Merbach, AE
    Kamalaprija, P
    Schaad, O
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (10) : 2488 - 2496
  • [9] Charbonniere LJ, 1998, CHEM-EUR J, V4, P485, DOI 10.1002/(SICI)1521-3765(19980310)4:3<485::AID-CHEM485>3.0.CO
  • [10] 2-8
12345