A train of carbon and DNPH-coated cartridges for the determination of carbonyls from C1 to C12 in air and emission samples

被引:39
作者
Possanzini, M [1 ]
Di Palo, V [1 ]
Brancaleoni, E [1 ]
Frattoni, M [1 ]
Ciccioli, P [1 ]
机构
[1] CNR, Ist Inquinamento Atmosfer, I-00016 Monterotondo, Italy
关键词
carbonyl compounds; analytical detection; sampling train; ambient concentrations; emission from biogenic sources;
D O I
10.1016/S1352-2310(00)00300-9
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A train of carbon and DNPH-coated cartridges set in series is proposed as a suitable method for determining all carbonyl compounds from C-1 to C-12 in air and emission samples. While the front traps are analyzed by GC-MS after thermal desorption, back-up cartridges are analyzed by HPLC-UV after liquid extraction. The method has been tested through laboratory and field experiments. Practical applications are reported and data obtained used for discussing the possible origin of volatile and semi-volatile compounds in forest areas of the Mediterranean basin. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:5311 / 5318
页数:8
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