Amphiphilic resin-supported ruthenium(II) complexes as recyclable catalysts for the hydrogenation of supercritical carbon dioxide

被引：56

作者：

Kayaki, Y

Shimokawatoko, Y

Ikariya, T ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Appl Chem, Grad Sch Sci & Engn, Meguro Ku, Tokyo 1528552, Japan

[2] Japan Sci & Technol Corp, CREST, Meguro Ku, Tokyo 1528552, Japan

[3] Japan Sci & Technol Corp, PRESTO, Meguro Ku, Tokyo 1528552, Japan

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2003年 / 345卷 / 1-2期

关键词：

amphiphilic resins; hydrogenation; immobilization; P ligands; ruthenium; supercritical carbon dioxide;

D O I：

10.1002/adsc.200390007

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Dichloro- and dihydridoruthenium(II) catalysts attached to an amphiphilic resin (PS - PEG) were prepared and tested for hydrogenation of supercritical carbon dioxide (scCO(2)) in the presence of dimethylamine leading to N,N-dimethylformamide (DMF). The supported catalysts were successfully recyclable with only moderate loss of activity.

引用

页码：175 / 179

页数：5

共 30 条

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