A new metal-organic open framework consisting of threefold parallel interwoven (6,3) nets

被引:67
作者
Suh, MP [1 ]
Choi, HJ [1 ]
So, SM [1 ]
Kim, BM [1 ]
机构
[1] Seoul Natl Univ, Ctr Mol Catalysis, Sch Chem & Mol Engn, Seoul 151747, South Korea
关键词
D O I
10.1021/ic025983a
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Threefold parallel interwoven (6,3) nets were assembled from Ni(II) cyclam complex and 1, 3,5-tris[2-(4-carboxyphenyl)-1-ethynyl]benzene. The network generates triangular voids of effective size ca. 18.4 x 14.7 x 9.5 Angstrom. It contains 35% free volume of the crystal volume and is stable up to 300 degreesC.
引用
收藏
页码:676 / 678
页数:3
相关论文
共 26 条
[1]  
Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO
[2]  
2-Z
[3]   Formation of discrete, functional assemblies and informational polymers through the hydrogen-bonding preferences of calixarene aryl and sulfonyl tetraureas [J].
Castellano, RK ;
Rebek, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (15) :3657-3663
[4]   Interwoven metal-organic framework on a periodic minimal surface with extra-large pores [J].
Chen, BL ;
Eddaoudi, M ;
Hyde, ST ;
O'Keeffe, M ;
Yaghi, OM .
SCIENCE, 2001, 291 (5506) :1021-1023
[5]   Selective binding of open frameworks assembled from nickel(II) macrocyclic complexes with organic and inorganic guests [J].
Choi, HJ ;
Lee, TS ;
Suh, MP .
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2001, 41 (1-4) :155-162
[6]  
Choi HJ, 1999, ANGEW CHEM INT EDIT, V38, P1405, DOI 10.1002/(SICI)1521-3773(19990517)38:10<1405::AID-ANIE1405>3.0.CO
[7]  
2-H
[8]   Self-assembly of molecular brick wall and molecular honeycomb from nickel(II) macrocycle and 1,3,5-benzenetricarboxylate: Guest-dependent host structures [J].
Choi, HJ ;
Suh, MP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (41) :10622-10628
[9]  
Fabbrizzi L, 1998, ANGEW CHEM INT EDIT, V37, P800, DOI 10.1002/(SICI)1521-3773(19980403)37:6<800::AID-ANIE800>3.0.CO
[10]  
2-U