An investigation of the role of the disparate redox states of the tetrathiafulvalene unit in modulating hydrogen bonding interactions in solution

被引：20

作者：

Boyd, ASF

Cooke, G

Duclairoir, FMA

Rotello, VM

机构：

[1] Heriot Watt Univ, Dept Chem, Ctr Biomimet Design & Synth, Sch Engn & Phys Sci, Edinburgh EH14 4AS, Midlothian, Scotland

[2] Univ Massachusetts, Dept Chem, Amherst, MA 01002 USA

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 02期

基金：

美国国家科学基金会; 英国工程与自然科学研究理事会;

关键词：

tetrathiafulvalene; recognition; electrochemistry;

D O I：

10.1016/S0040-4039(02)02574-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We have investigated the electrochemically controlled hydrogen bonding interactions between tetrathiafulvalene host 3 and guests 4 or 5. Stabilisation of the 3(+.) state is dependent upon the nature of the guest species, whereas both guests prevent precipitation of the electrochemically generated 3(2+) species at the working electrode via hydrogen bonded molecular recognition processes. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：303 / 306

页数：4

共 21 条

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