Functionalizing the surface of II-VI clusters:: redox active centres on the adamantoid complex [Cd4Cl4{μ-(SeC5H4)Fe(C5H5)}6]2-

被引:28
作者
Lebold, TP [1 ]
Stringle, DLB [1 ]
Workentin, MS [1 ]
Corrigan, JF [1 ]
机构
[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada
关键词
D O I
10.1039/b302829a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Trimethylsilylselenoferrocene 1 has been prepared in good yield. The reactive silyl group on 1 is used as a driving force for the synthesis [Cl4Cd4{mu(2)-Se(C5H4)Fe(C5H5)}(6)](2-) 2, a Cd4Se6 adamantoid cluster with six surface ferrocenyl groups.
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页码:1398 / 1399
页数:2
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