Palladium-Catalyzed One-Pot Conversion of Aldehydes to Amides

被引：99

作者：

Ali, Md Ashif ^{[1
]}

Punniyamurthy, Tharmalingam ^{[1
]}

机构：

[1] Indian Inst Technol Guwahati, Dept Chem, Gauhati 781039, India

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2010年 / 352卷 / 2-3期

关键词：

aldehydes; homogeneous catalysis; one-pot synthesis; palladium(II) acetate; primary amides; STEP BECKMANN REARRANGEMENT; SOLVENT-FREE; ALDOXIMES; OXIDATION; ACCELERATION; ALCOHOLS; COMPLEX;

D O I：

10.1002/adsc.200900799

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The palladium-catalyzed one-pot conversion of aldehydes into primary amides in the presence of hydroxylamine hydrochloride in aqueous dimethyl sulfoxide (DMSO) at moderate temperature is described. The process is selective and free from the addition of an external chelating ligand.

引用

页码：288 / 292

页数：5

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