Liquid-crystal templating of conducting polymers

被引:119
作者
Hulvat, JF [1 ]
Stupp, SI [1 ]
机构
[1] Northwestern Univ, Feinberg Sch Med, Dept Mat Sci & Engn, Dept Chem, Evanston, IL 60208 USA
关键词
amphiphiles; electrochemistry; liquid crystals; polymerization; self-assembly;
D O I
10.1002/anie.200390206
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Mimicking the texture and anisotropy of the template, birefringent conducting polymer films (see picture) have been obtained by electropolymerization of 3,4-ethyldioxythiophene (EDOT) within a hexagonal lyotropic liquid crystal. Using a self-assembled template to control molecular orientation in conducting polymers could enhance electronic and optical properties.
引用
收藏
页码:778 / 781
页数:4
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