Synthesis, crystal and molecular structure of the first indium trihydride complex, [InH3{CN(Pri)C2Me2N(Pri)}]

被引:41
作者
Hibbs, DE
Hursthouse, MB
Jones, C
Smithies, NA
机构
[1] Univ Coll Swansea, Dept Chem, Swansea SA2 8PP, W Glam, Wales
[2] Univ Wales, Dept Chem, EPSRC Xray Crystallog Serv, Cardiff CF1 3TB, S Glam, Wales
关键词
D O I
10.1039/a801118d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of either [InH3(NMe3)] or LiInH4 with an excess of the imidazol-2-ylidene carbene, :CN(Pr-i)C2Me2N-(Pr-i), affords the first example of an indium trihydride complex, [InH3{CN(Pr-i)C2Me2N(Pr-i)}], the X-ray crystal structure of which is described.
引用
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页码:869 / 870
页数:2
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