Size and shape control of monodisperse FePt nanoparticles

被引:146
作者
Nandwana, Vikas [1 ]
Elkins, Kevin E. [1 ]
Poudyal, Narayan [1 ]
Chaubey, Girija S. [1 ]
Yano, Kazuaki [1 ]
Liu, J. Ping [1 ]
机构
[1] Univ Texas, Dept Phys, Arlington, TX 76019 USA
关键词
D O I
10.1021/jp068330e
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Morphological control of FePt nanoparticles has been systematically studied. By varying synthetic parameters including precursors, solvents, amount of surfactants, and heating rate of the solution, the particle size from 2 to 9 nm can be tuned with 1 nm accuracy. While most particles are spherical in shape, cubic particles can be obtained when particles are greater than 7 nm. Rod-shape nanoparticles have also been obtained. The as-synthesized nanoparticles are found to be superparamagnetic at room temperature and their blocking temperature is size dependent that increases with particle size. After annealing in a reducing atmosphere, the nanoparticles form hard magnetic films with ordered fct structure and high coercivity up to 2.7 T.
引用
收藏
页码:4185 / 4189
页数:5
相关论文
共 40 条
[1]   One-step synthesis of FePt nanoparticles with tunable size [J].
Chen, M ;
Liu, JP ;
Sun, SH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (27) :8394-8395
[2]   Synthesis of spherical FePd and CoPt nanoparticles [J].
Chen, M ;
Nikles, DE .
JOURNAL OF APPLIED PHYSICS, 2002, 91 (10) :8477-8479
[3]   Polyol-process-derived CoPt nanoparticles: Structural and magnetic properties [J].
Chinnasamy, CN ;
Jeyadevan, B ;
Shinoda, K ;
Tohji, K .
JOURNAL OF APPLIED PHYSICS, 2003, 93 (10) :7583-7585
[4]   Nanocrystal superlattices [J].
Collier, CP ;
Vossmeyer, T ;
Heath, JR .
ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1998, 49 :371-404
[5]  
Cullity B. D., 1972, INTRO MAGNETIC MAT
[6]   Monodisperse face-centred tetragonal FePt nanoparticles with giant coercivity [J].
Elkins, K ;
Li, D ;
Poudyal, N ;
Nandwana, V ;
Jin, ZQ ;
Chen, KH ;
Liu, JP .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2005, 38 (14) :2306-2309
[7]  
Fried T, 2001, ADV MATER, V13, P1158, DOI 10.1002/1521-4095(200108)13:15<1158::AID-ADMA1158>3.0.CO
[8]  
2-6
[9]  
Hafeli U., 1997, Scientific and Clinical Applications of Magnetic Carriers, DOI DOI 10.1007/s10439-009-9660-y
[10]   Ordered structures in Fe3O4 kerosene-based ferrofluids [J].
Hong, CY ;
Jang, IJ ;
Horng, HE ;
Hsu, CJ ;
Yao, YD ;
Yang, HC .
JOURNAL OF APPLIED PHYSICS, 1997, 81 (08) :4275-4277