Anomalous structure-luminescence relationship in phosphorescent gold(I) isonitrile neutral complexes

被引：34

作者：

Elbjeirami, O

Omary, MA ^{[1
]}

Stender, M

Balch, AL

机构：

[1] Univ N Texas, Dept Chem, Denton, TX 76203 USA

[2] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

DALTON TRANSACTIONS | 2004年 / 20期

关键词：

D O I：

10.1039/b410657a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new compound that exhibits the shortest intermolecular Au...Au distance ever reported for neutral RNCAuX complexes is found to exhibit a counterintuitive higher-energy Au-centered phosphorescence than that in an analogous compound with a much longer Au...Au distance, presumably due to a different extent of excited-state distortion in dimers vs. extended chains.

引用

收藏

页码：3173 / 3175

页数：3

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