Charge-transfer salts containing cyclic perfluorinated anions

被引：1

作者：

Briscoe, MW

Chambers, RD

Clegg, W

Gibson, VC

Mullins, SJ

Vaughan, JFS

机构：

[1] UNIV DURHAM,DEPT CHEM,SCI LABS,DURHAM DH1 3LE,ENGLAND

[2] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1996年 / 76卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

charge-transfer salts; perfluorinated cyclic alkenes; crystal structure; cyclic voltammetry;

D O I：

10.1016/0022-1139(95)03335-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Perfluorobicyclopentenyl (1a) and -butenyl (2a) react with decamethylferrocene (3), to give charge-transfer salts 4 and 5, respectively; perfluorohexakis (trifluoromethyl) cyclo-pentadiene (6) forms a salt (8) containing the C-5(CF3)(5) anion, Crystal structures of the salts 4 and 5 have been determined; both contain centrosymmetric trans-diene radical anions.

引用

页码：1 / 2

页数：2

共 3 条

[1] REACTIONS INVOLVING FLUORIDE-ION .38. NEW FLUORINATED DIENES BY DEFLUORINATION [J].