Carboxylate and carboxylic acid recognition by tin(IV) porphyrins

被引：59

作者：

Hawley, JC

Bampos, N

Abraham, RJ

Sanders, JKM

机构：

[1] Univ Cambridge, Cambridge Ctr Mol Recognit, Chem Lab, Cambridge CB2 1EW, England

[2] Univ Liverpool, Dept Chem, Liverpool L69 3BX, Merseyside, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 06期

关键词：

D O I：

10.1039/a709069b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The scope of carboxylate binding by tin(IV) porphyrins and the solution geometries of the resulting complexes have been explored using H-1 NMR spectroscopy; ring current induced shifts and competition experiments indicate the operation of an attractive anthracene-porphyrin interaction; outer sphere carboxylic acid complexes of dihydroxy tin(IV) porphyrins have been characterised, apparently for the first time.

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页码：661 / 662

页数：2

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