Discovering and verifying elusive fullerene cage isomers:: Structures of C2-p11-(C74-D3h)(CF3)12 and C2-p11-(C78-D3h(5))(CF3)12

被引：47

作者：

Shustova, Natalia B.

Newell, Brian S.

Miller, Susie M.

Anderson, Oren P.

Bolskar, Robert D.

Seppelt, Konrad

Popov, Alexey A.

Boltalina, Olga V. ^{[1
]}

Strauss, Steven H.

机构：

[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA

[2] TDA Res Inc, Wheat Ridge, CO 80033 USA

[3] Free Univ Berlin, Inst Anorgan & Analyt Chem, D-14195 Berlin, Germany

[4] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 22期

关键词：

C-74; C-78; fullerenes; trifluoromethyl substituents; X-ray diffraction;

D O I：

10.1002/anie.200604968

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Two in a million: The solid-state structures of C 2-symmetric isomers of C74(CF3)12 (see picture) and C78(CF3)12 have been solved by X-ray crystallography. They verify the structures of the hollow C 74-D3h and C78-D3h(5) cages, and exhibit a (para)11 ribbon of edge-sharing p-C6(CF 3)2 hexagons on the surface of the fullerenes. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

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收藏

页码：4111 / 4114

页数：4

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