Amine products and catalyst poisoning in the homogeneous H2 hydrogenation of Imines catalyzed by the [Rh(COD)(PPh3)2]PF6 precursor

被引：38

作者：

Marcazzan, P ^{[1
]}

Patrick, BO ^{[1
]}

James, BR ^{[1
]}

机构：

[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 06期

关键词：

METAL-COMPLEXES; RHODIUM; LIGANDS;

D O I：

10.1021/om020992c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The H-2 hydrogenations of PhN=CHPh and PhCH2N=CHPh are catalyzed by the precursor [Rh(COD)(PPh3)(2)]PF6. However, the amine product PhNHCH2Ph poisons the catalyst by coordination to the Rh through an arene moiety, while the other amine product, (PhCH2)(2)NH, forms a labile N-bonded species that does not poison the catalyst system.

引用

页码：1177 / 1179

页数：3

共 14 条

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