Influence of hydrogen preactivation on the linoleic acid isomerization properties of supported ruthenium catalyst

被引:14
作者
Bernas, A [1 ]
Murzin, DY [1 ]
机构
[1] Abo Akad Univ, Lab Ind Chem, Proc Chem Grp, FIN-20500 Turku, Finland
来源
REACTION KINETICS AND CATALYSIS LETTERS | 2003年 / 78卷 / 01期
关键词
linoleic acid; CLA; ruthenium catalyst; isomerization;
D O I
10.1023/A:1022553027885
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Isomerization of linoleic acid over carbon supported ruthenium and the influence of catalyst preactivation under hydrogen were investigated in a batch reactor. Chemisorbed hydrogen increased the catalytic activity but did also suppress the isomerization selectivity due to double bond hydrogenation.
引用
收藏
页码:3 / 10
页数:8
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