Proton exchange membrane fuel cell from low temperature to high temperature: Material challenges

被引:477
作者
Shao, Yuyan [1 ]
Yin, Geping
Wang, Zhenbo
Gao, Yunzhi
机构
[1] Case Western Reserve Univ, Dept Macromol Sci & Engn, Cleveland, OH 44106 USA
[2] Harbin Inst Technol, Dept Appl Chem, Harbin 150001, Peoples R China
[3] Univ Puerto Rico, Dept Chem, Fac Nat Sci, Rio Piedras, PR 00931 USA
关键词
high-temperature proton exchange membrane fuel cell; electrocatalysts; polymer electrolyte; bipolar plates; durability; material compatibility;
D O I
10.1016/j.jpowsour.2007.02.065
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Proton exchange membrane fuel cell (PEMFC) is considered as one promising clean and highly efficient power generation technology in 21st century. Current PEMFC operating at low temperatures (<80 degrees C) encounters several difficulties, such as CO tolerance, heat rejection, which can be, to a great extent, surmounted at higher temperatures (120-150 degrees C). However, the higher temperature conditions are much more challenging to implement, particularly with regards to the durability of the cell component materials. This paper overviews the drivers behind the interest in high-temperature PEMFC, and the challenges in developing novel materials to enable high-temperature PEMFC, including cell component durability (catalysts, polymer, bipolar plates, etc.), candidate polyelectrolytes for the electrode catalyst layer, and material compatibility in novel membrane electrode assembly (MEA), and provides an insight into the material research and development for PEMFC. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:235 / 242
页数:8
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