Odor and (bio)diversity: Single enantiomers of chiral fragrant substances

被引:34
作者
Abate, A [1 ]
Brenna, E [1 ]
Fuganti, C [1 ]
Gatti, FG [1 ]
Serra, S [1 ]
机构
[1] CNR, Ist Chim Riconoscimento Mol, Politecn, Dipartimento Chim Mat & Ingn Chim, I-20131 Milan, Italy
关键词
D O I
10.1002/cbdv.200490145
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Our sense of smell is enantioselective. This review reports interesting examples of single stereoisomers of natural and synthetic odorants, prepared via bioorganic routes, that support this statement. This article is the summary of a talk given at the Flavours & Fragrances 2004 conference in Manchester at the MCC/UMIST, 1214 May, 2004.
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收藏
页码:1888 / 1898
页数:11
相关论文
共 27 条
[1]   Preparation of the enantiomerically enriched isomers of the odorous cyclic ethers Clarycet®, Florol®, and Rhubafuran® by enzymatic catalysis [J].
Abate, A ;
Brenna, E ;
Fronza, G ;
Fuganti, C ;
Gatti, FG ;
Serra, S ;
Zardoni, E .
HELVETICA CHIMICA ACTA, 2004, 87 (04) :765-780
[2]   Enzyme-mediated preparation of chiral 1,3-dioxane odorants [J].
Abate, A ;
Brenna, E ;
Fronza, G ;
Fuganti, C ;
Ronzani, S ;
Serra, S .
HELVETICA CHIMICA ACTA, 2003, 86 (03) :592-606
[3]   Biocatalysed synthesis of the enantiotners of the floral odorant Florhydral® [J].
Abate, A ;
Brenna, E ;
Negri, CD ;
Fuganti, C ;
Serra, S .
TETRAHEDRON-ASYMMETRY, 2002, 13 (08) :899-904
[4]  
ABATE A, IN PRESS J ORG CHEM
[5]   Enantioselective perception of chiral odorants [J].
Brenna, E ;
Fuganti, C ;
Serra, S .
TETRAHEDRON-ASYMMETRY, 2003, 14 (01) :1-42
[6]  
Brenna E, 2002, EUR J ORG CHEM, V2002, P967, DOI 10.1002/1099-0690(200203)2002:6<967::AID-EJOC967>3.0.CO
[7]  
2-E
[8]  
Brenna E, 2001, HELV CHIM ACTA, V84, P3650, DOI 10.1002/1522-2675(20011219)84:12<3650::AID-HLCA3650>3.0.CO
[9]  
2-5
[10]   Biocatalyzed preparation of the optically enriched stereoisomers of 4-methyl-2-phenyl-tetrahydro-2H-pyran (Doremox®) [J].
Brenna, E ;
Fuganti, C ;
Ronzani, S ;
Serra, S .
CANADIAN JOURNAL OF CHEMISTRY, 2002, 80 (06) :714-723