Mechanical properties of cross-linked hyaluronic acid/poly-(L-lysine) multilayer films

被引:45
作者
Collin, D
Lavalle, P
Garza, JM
Voegel, JC
Schaaf, P
Martinoty, P
机构
[1] Univ Strasbourg 1, INSERM, Fac Chirurgie Dent, Unite 595, F-67085 Strasbourg, France
[2] Univ Strasbourg 1, Lab Dynam Fluides Complexes, CNRS, UMR 7506, F-67070 Strasbourg, France
[3] Fac Med Vandoeuvre Nancy, CNRS, UMR 7563, LEMTA, F-54500 Vandoeuvre Les Nancy, France
[4] Inst Charles Sadron, CNRS, UPR 22, F-67083 Strasbourg, France
关键词
D O I
10.1021/ma048683g
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A piezorheometer was used to provide the first study of the shear modulus of poly(L-lysine)/hyaluronic acid (PLL/HA) multilayer films. It was found that this type of rheometer allows the first determination of the complex shear modulus over a wide frequency range, from 0.2 Hz to a few Kilohertz. The (PLL/HA)n multilayer films were built up by sequential dipping of the substrate into polyanion and polycation solutions. It was concluded that the technique requires films with thicknesses ranging from 10 to 100 μm and is thus well adapted for the study of thick exponentially growing films.
引用
收藏
页码:10195 / 10198
页数:4
相关论文
共 30 条
[1]   Buildup of exponentially growing multilayer polypeptide films with internal secondary structure [J].
Boulmedais, F ;
Ball, V ;
Schwinte, P ;
Frisch, B ;
Schaaf, P ;
Voegel, JC .
LANGMUIR, 2003, 19 (02) :440-445
[2]   Dynamic macroscopic heterogeneities in a flexible linear polymer melt [J].
Collin, D ;
Martinoty, P .
PHYSICA A-STATISTICAL MECHANICS AND ITS APPLICATIONS, 2003, 320 :235-248
[3]   Fuzzy nanoassemblies: Toward layered polymeric multicomposites [J].
Decher, G .
SCIENCE, 1997, 277 (5330) :1232-1237
[4]   BUILDUP OF ULTRATHIN MULTILAYER FILMS BY A SELF-ASSEMBLY PROCESS .1. CONSECUTIVE ADSORPTION OF ANIONIC AND CATIONIC BIPOLAR AMPHIPHILES ON CHARGED SURFACES [J].
DECHER, G ;
HONG, JD .
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1991, 46 :321-327
[5]   Elastic properties of polyelectrolyte capsules studied by atomic-force microscopy and RICM [J].
Dubreuil, F ;
Elsner, N ;
Fery, A .
EUROPEAN PHYSICAL JOURNAL E, 2003, 12 (02) :215-221
[6]   Thin polymer layers formed by polyelectrolyte multilayer techniques on biological surfaces [J].
Elbert, DL ;
Herbert, CB ;
Hubbell, JA .
LANGMUIR, 1999, 15 (16) :5355-5362
[7]   Elasticity of hollow polyelectrolyte capsules prepared by the layer-by-layer technique [J].
Gao, C ;
Donath, E ;
Moya, S ;
Dudnik, V ;
Möhwald, H .
EUROPEAN PHYSICAL JOURNAL E, 2001, 5 (01) :21-27
[8]   Compliant, robust, and truly nanoscale free-standing multilayer films fabricated using spin-assisted layer-by-layer assembly [J].
Jiang, CY ;
Markutsya, S ;
Tsukruk, VV .
ADVANCED MATERIALS, 2004, 16 (02) :157-+
[9]   Micromechanics of surface-grafted hyaluronic acid gels [J].
Ladam, G ;
Vonna, L ;
Sackmann, E .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (34) :8965-8971
[10]   Comparison of the structure of polyelectrolyte multilayer films exhibiting a linear and an exponential growth regime: An in situ atomic force microscopy study [J].
Lavalle, P ;
Gergely, C ;
Cuisinier, FJG ;
Decher, G ;
Schaaf, P ;
Voegel, JC ;
Picart, C .
MACROMOLECULES, 2002, 35 (11) :4458-4465