Homoleptic lanthanide triple-deckers of 5,15-diazaporphyrin with D2h symmetry

被引：30

作者：

Pan, N

Bian, YZ

Fukuda, T

Yokoyama, M

Li, RJ

Neya, S ^{[1
]}

Jiang, JZ

Kobayashi, N

机构：

[1] Chiba Univ, Grad Sch Pharmaceut Sci, Dept Phys Chem, Chiba 2638522, Japan

[2] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan

[3] Shandong Univ, Dept Chem, Jinan 250100, Peoples R China

来源：

INORGANIC CHEMISTRY | 2004年 / 43卷 / 26期

关键词：

D O I：

10.1021/ic048744r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel homoleptic diazaporphyrinato lanthanide sandwich complexes M-2(DAP)(3) [M = Ce (1), Eu (2); DAP = 2,8,12,18-tetraethyl-3,7,13,17-tetramethyl-5,15-diazaporphyrinate] were synthesized by a one-pot reaction of the corresponding M(acac)(3).nH(2)O (acac = acetylacetonate) with metal-free D-2h type diazaporphyrin, H(2)DAP. The spectroscopic and electrochemical properties are compared with those of complexes based on D-4h symmetry porphyrin ligands.

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收藏

页码：8242 / 8244

页数：3

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