Characterization of some O-acetylated saponins from Quillaja saponaria Molina

被引:33
作者
Guo, SJ [1 ]
Kenne, L [1 ]
机构
[1] Swedish Univ Agr Sci, Dept Chem, SE-75007 Uppsala, Sweden
关键词
Quillaja saponaria Molina; structural analysis; saponins; quillaic acid; acetyl group;
D O I
10.1016/S0031-9422(00)00161-8
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Sixteen saponins were identified from a bark extract of Quillaja suponaria ia Molina. The compounds were characterized, using NMR spectroscopy, mass spectrometry and monosaccharide analysis, as quillaic acid substituted at C-3 with oligosaccharides consisting of a disaccharide. beta-D-Galp-(1 --> 2)-beta-D-GlcpA substituted with either D-xylose or L-rhamnose and at C-28 with complex oligosaccharide structures consisting of a disaccharide, alpha-L-Rhap-(1 --> 2)-4-O-acetyl-beta-D-Fucp, substituted with various amount of D-xylose, D-glucose, D-apiose, and L-rhamnose. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:615 / 623
页数:9
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