Heat capacity of the restricted primitive model near criticality

被引:44
作者
Valleau, J [1 ]
Torrie, G
机构
[1] Univ Toronto, Dept Chem, Chem Phys Theory Grp, Toronto, ON M5S 3H6, Canada
[2] Royal Mil Coll Canada, Dept Chem & Chem Engn, Kingston, ON K7K 7B4, Canada
关键词
D O I
10.1063/1.475954
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This concerns the supercritical heat capacity of the "restricted primitive model" of Coulombic systems, one aspect of a more general attempt to study the phase transition and critical behavior of this model using thermodynamic-scaling Monte Carlo techniques. We see no indication of Ising-type divergence of the heat capacity; the strength of the evidence in this regard is discussed. (C) 1998 American Institute of Physics.
引用
收藏
页码:5169 / 5172
页数:4
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