Two-dimensional, open-pored, mesoscopic titania layers using polymeric nanoparticle monolayers as a template

被引:43
作者
Cho, YH
Cho, G
Lee, JS
机构
[1] Gwangju Inst Sci & Technol, Ctr Frontier Mat, Dept Mat Sci & Engn, Kwangju 500712, South Korea
[2] Sunchon Natl Univ, Dept Chem Engn, Sunchon 540742, South Korea
[3] Sunchon Natl Univ, Nanotechnol Ctr, Sunchon 540742, South Korea
关键词
D O I
10.1002/adma.200400249
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Open-pored mesoscopic 2D titania layers (see Figure) were fabricated by using a nanoparticle layer as a template. Monodisperse polymer particles approximately 60 nm in diameter were spontaneously formed by dissolving polystyrene-b-poly(N-methyl-2-vinyl-pyridinium iodide) in toluene. These particles self-assembled at the air-water interface to form well-ordered monolayers. which were then used as templates in a sol-gel reaction to form porous 2D titania layers with a pore size of similar to 55 nm.
引用
收藏
页码:1814 / +
页数:5
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