Observation of exceptionally strong binding of molecular hydrogen in a porous material:: Formation of an η2-H2 complex in a Cu-exchanged ZSM-5 zeolite

被引：62

作者：

Georgiev, Peter A.

Albinati, Alberto

Mojet, Barbara L.

Ollivier, Jacques

Eckert, Juergen

机构：

[1] Univ Milan, Dept Struct Chem, I-20123 Milan, Italy

[2] Univ Twente, Inst Mech Proc & Cntrol, Fac Sci & Technol, NL-7500 AE Enschede, Netherlands

[3] Inst Laue Langevin, F-38042 Grenoble, France

[4] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA

[5] LANSCE LC, Los Alamos Natl Lab, Los Alamos, NM 87545 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 26期

关键词：

D O I：

10.1021/ja072240l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have measured the rotational tunneling spectrum of a Cu-ZSM-5 zeolite after loading with H-2, by means of inelastic incoherent neutron scattering. The peaks at +/- 0.80 and +/- 1.73 cm(-1) unambiguously demonstrate the formation of a strongly bound Cu(eta(2)-H-2) complex.

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页码：8086 / +

页数：3

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