Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorus oxoanions

被引：19

作者：

Burke, LT

Freire, EH

Holland, R

Jeffery, JC

Leedham, AP

Russell, CA

Steiner, A

Zagorski, A

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

[2] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 18期

关键词：

D O I：

10.1039/b004192k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of PCl3 with 3 equivalents of 2-methoxyaniline in THF/NEt3, followed by metallation with (BuLi)-Li-n (2 equivalents) yields a complex [Li2P(H)(NR)(3)](2) 1 (R = 2-methoxyphenyl), whose tris imido phosphonate anion is the imido analogue of the phosphite anion, [HPO3](2-).

引用

收藏

页码：1769 / 1770

页数：2

相关论文

共 27 条

[1] A monomeric samarium bis(iminophosphorano) chelate complex with a Sm=C bond [J].

Aparna, K ;

Ferguson, M ;

Cavell, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (04) :726-727

[2]

BINDER H, 1974, CHEM BER-RECL, V107, P205, DOI 10.1002/cber.19741070126

[3] SPONTANEOUS FORMATION OF A DICOORDINATE IMINOPHOSPHINE FROM A TRICOORDINATE TRIAMINOPHOSPHINE VIA A TETRACOORDINATE PHOSPHORANE [J].

BURFORD, N ;

CLYBURNE, JAC ;

MASON, S ;

RICHARDSON, JF .

INORGANIC CHEMISTRY, 1993, 32 (23) :4988-4989

[4] Phosphoraneiminato complexes of transition metals [J].

Dehnicke, K ;

Krieger, M ;

Massa, W .

COORDINATION CHEMISTRY REVIEWS, 1999, 182 :19-65

[5] MONOMER AND DIMER 1,3-DIAZA-2-PHOSPHAALLYLLITHIUM COMPLEXES - STRUCTURES AND AMBIDENT REACTIVITY [J].

DETSCH, R ;

NIECKE, E ;

NIEGER, M ;

SCHOELLER, WW .

CHEMISCHE BERICHTE-RECUEIL, 1992, 125 (05) :1119-1124

[6] PHOSPHORUS-NITROGEN BONDS - QUANTOCHEMICAL STUDY OF NEUTRAL AND IONIC MODELS OF H3PNH, H3PNH2+, H2PNH3+, H2PNH- AND HPNH2- [J].

GONBEAU, D ;

PFISTERGUILLOUZO, G ;

MAZIERES, MR ;

SANCHEZ, M .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1985, 63 (11) :3242-3248

[7] CRYSTAL HANDLING AT LOW-TEMPERATURES [J].

KOTTKE, T ;

STALKE, D .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1993, 26 :615-619

[8]

NIECKE E, 1994, ANGEW CHEM INT EDIT, V33, P2111, DOI 10.1002/anie.199421111

[9]

NIECKE E, 1994, ANGEW CHEM, V106, P2170

[10]

NOVOSAD J, 1994, ENCY INORGANIC CHEM, V6, P3169