Gyroxanthin - the first allenic acetylenic carotenoid

被引：24

作者：

Bjornland, T ^{[1
]}

Fiksdahl, A ^{[1
]}

Skjetne, T ^{[1
]}

Krane, J ^{[1
]}

Liaaen-Jensen, S ^{[1
]}

机构：

[1] Norwegian Univ Sci & Technol, Organ Chem Labs, Dept Biol & Chem, N-7491 Trondheim, Norway

来源：

TETRAHEDRON | 2000年 / 56卷 / 46期

关键词：

gyroxanthin; carotenoid; allenic; acetylenic; Gyrodinium;

D O I：

10.1016/S0040-4020(00)00757-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Selected recent studies on marine allenic and acetylenic carotenoids are focused on. The structure elucidation of gyroxanthin, (3S,5R,6S,3'S,5'R,6'R)-5,6-epoxy-6,7,7',8'-tetradehydro-5',6'-tetrahydro-beta,beta -carotene-3,19,3',5'-tetrol, is reported in detail and in historical perspective. Gyroxanthin occurs as a diester (19-dodecanoate 3'-acetate) in the dinoflagellate Gymnodinium galatheanum. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：9047 / 9056

页数：10

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