Novel 2 V rocking-chair lithium battery based on nano-crystalline titanium dioxide

被引：94

作者：

Exnar, I ^{[1
]}

Kavan, L

Huang, SY

Gratzel, M

机构：

[1] Renata AG, CH-4452 Itingen, Switzerland

[2] J Heyrovsky Inst Phys Chem & Electrochem, CR-18223 Prague, Czech Republic

[3] Swiss Fed Inst Technol, CH-1015 Lausanne, Switzerland

来源：

JOURNAL OF POWER SOURCES | 1997年 / 68卷 / 02期

关键词：

titanium dioxide; insertion material; rocking-chair batteries; lithium batteries;

D O I：

10.1016/S0378-7753(96)02581-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel type of 2 V rocking-chair lithium batteries with nano-crystalline TiO2 (anatase) as the negative and LiNi0.5Co0.5O2 as the positive electrode with LiN(CF3SO2)(2)+ethylene carbonate/dimethoxyethane electrolyte has been studied. The closed R921 button cells showed excellent cycling performance and a charge density of about 50 mAh/g. The advantages of the specific porous morphology of nano-crystalline insertion materials for Li insertion and release are discussed. (C) 1997 Elsevier Science S.A.

引用

页码：720 / 722

页数：3

共 7 条

[1] ROCKING CHAIR LITHIUM BATTERY BASED ON NANOCRYSTALLINE TIO2 (ANATASE)
HUANG, SY
KAVAN, L
EXNAR, I
GRATZEL, M
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (09) : L142 - L144
[2] Huang SY, 1995, ACTIVE PASSIVE ELEC, V18, P23
[3] DIFFUSION OF LITHIUM IN THE TIO2 CATHODE OF A LITHIUM BATTERY
KANAMURA, K
YUASA, K
TAKEHARA, Z
[J]. JOURNAL OF POWER SOURCES, 1987, 20 (1-2) : 127 - 134
[4] STUDY OF NANOCRYSTALLINE TIO2 (ANATASE) ELECTRODE IN THE ACCUMULATION REGIME
KAVAN, L
KRATOCHVILOVA, K
GRATZEL, M
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 394 (1-2): : 93 - 102
[5] Nanocrystalline TiO2 (anatase) electrodes: Surface morphology, adsorption, and electrochemical properties
Kavan, L
Gratzel, M
Rathousky, J
Zukal, A
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (02) : 394 - 400
[6] OHZUKU T, 1982, ELECTROCHIM ACTA, V27, P1263
[7] ELECTROCHEMISTRY OF ANATASE TITANIUM-DIOXIDE IN LITHIUM NONAQUEOUS CELLS
OHZUKU, T
KODAMA, T
HIRAI, T
[J]. JOURNAL OF POWER SOURCES, 1985, 14 (1-3) : 153 - 166

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