Optical absorption spectra of linear and cyclic thiophenes-selection rules manifestation

被引：78

作者：

Bednarz, M

Reineker, P

Mena-Osteritz, E

Bäuerle, P

机构：

[1] Univ Ulm, Theoret Phys Abt, D-89069 Ulm, Germany

[2] Univ Ulm, Abt Organ Chem 2, D-89069 Ulm, Germany

来源：

JOURNAL OF LUMINESCENCE | 2004年 / 110卷 / 04期

关键词：

oligothiophenes; cyclothiopbenes; Frenkel excitons; optical absorption;

D O I：

10.1016/j.jlumin.2004.08.013

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

We theoretically study the size-dependent relation between absorption spectra of thiophene-based oligomers and the corresponding cyclothiophenes. In our approach based on a Frenkel exciton Hamiltonian, we demonstrate that the geometry and selection rules determine the observed relations between the spectra. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：225 / 231

页数：7

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