Structural refinement of Ag-Fe blends during high energy ball milling

被引:2
作者
Angiolini, M
Deriu, A
Malizia, F
Mazzone, G
Montone, A
Ronconi, F
Vittori-Antisari, M
Pedersen, JS
机构
[1] ENEA, CR Casaccia, INN, NUMA, I-00100 Rome, Italy
[2] Univ Parma, Dipartimento Fis, I-43100 Parma, Italy
[3] Univ Parma, INFM, I-43100 Parma, Italy
[4] Univ Ferrara, Dipartmento Fis, I-44100 Ferrara, Italy
[5] Riso Natl Lab, Roskilde, Denmark
来源
MECHANICALLY ALLOYED, METASTABLE AND NANOCRYSTALLINE MATERIALS, PART 1 | 1998年 / 269-2卷
关键词
nanostructures; mechanical alloying; immiscible systems;
D O I
10.4028/www.scientific.net/MSF.269-272.397
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The effect of high energy ball milling on the structural refinement of the binary system Ag-Fe has been studied by Transmission and Scanning Electron Microscopy, Small Angle Neutron Scattering and Mossbauer spectroscopy. Samples containng 10 wt% of Fe were submitted to high energy ball milling for times up to 50 hours. The process produces a fine dispersion of Fe into the Ag matrix; the size distribution function is quite broad with an average radius of the order of a few nm. The minimum average particle size is obtained after about 10 hours of milling, longer term processing leads to a detectable particle coarsening. TEM analyses give evidence of a well defined orientation relationships between the Fe particles and the Ag matrix. Mossbauer spectroscopy reveals a modification of the hyperfine field experienced by the Fe atoms only for short term milling. On the basis of the experimental results one can assume that the fine dispersion of Fe into the Ag matrix occurs by mutual solubilisation probably induced by plastic shear, followed by fast decomposition by precipitation. After this step, further milling can induce only coarsening of the microstructure.
引用
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页码:397 / 402
页数:6
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