Bis(1,10-phenanthroline-N,N′)copper(II) tetrathionate and tris(1,10-phenanthroline-N,N′)copper(II) tetrathionate pentahydrate

被引：18

作者：

Freire, E ^{[1
]}

Baggio, S

Baggio, R

Garland, MT

机构：

[1] Univ Nacl Patagonia, RA-9120 Puerto Madryn, Chubut, Argentina

[2] CONICET, CenPat, RA-9120 Puerto Madryn, Chubut, Argentina

[3] Comis Nacl Energia Atom, Dept Fis, RA-1429 Buenos Aires, DF, Argentina

[4] Univ Chile, Fac Ciencias Fis & Matemat, Dept Fis, Santiago, Chile

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270197016284

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structures of [Cu(C12H8N2)(2)(S4O6)], (I), and [CU(C12H8N2)(3)](S4O6).5H(2)O, (II), are reported. Compound pound (I) consists of infinite polymeric chains where copper displays a typical (4+2) coordination and prepare S4O6 connects Cu(phen)(2) (phen is phenanthroline) units through rather long Cu...O contacts. Compound (II), instead, has a purely ionic character displaying [Cu(phen)(3)](2+) and S4O62- monomeric units. Equatorial and apical bonds in the copper coordination spheres have mean values of 2.003(5)/2.467(12) and 2.056 (3)/2.311(13)Angstrom for (I) and (II), respectively. Some short O...OW contacts in (II) suggest the existence of hydrogen bonding involving some of the water molecules of hydration.

引用

页码：464 / 468

页数：5

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