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Vesicles and polymerized vesicles from thiophene-containing rod-coil block copolymers

被引：289
作者：
Vriezema, DM
Hoogboom, J
Velonia, K
Takazawa, K
Christianen, PCM
Maan, JC
Rowan, AE
Nolte, RJM
机构：
[1] Catholic Univ Nijmegen, Dept Organ Chem, NL-6525 ED Nijmegen, Netherlands
[2] Catholic Univ Nijmegen, High Field Magnet Lab, NL-6525 ED Nijmegen, Netherlands
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 07期
关键词：
block copolymers; enzymes; polyisocyanides; vesicles;
D O I：
10.1002/anie.200390204
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Spontaneous formation of vesicles in both organic solvents and water is observed for new rod-coil-type diblock copolymers containing thiophene groups. The thiophene groups located in the skin of the aggregates can couple to give polymerized vesicles (see picture and cover picture). The vesicles are capable of including enzymes, which results in catalytically active microreactors that are permeable to substrate molecules.
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收藏
页码：772 / 776
页数：5
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