A new efficient method for the conversion of aldehydes into nitriles using ammonia and hydrogen peroxide

被引:64
作者
Erman, MB [1 ]
Snow, JW [1 ]
Williams, MJ [1 ]
机构
[1] Millennium Specialty Chem, Jacksonville, FL 32201 USA
关键词
nitriles; aldehydes; ammonia; hydrogen peroxide; catalysis; copper;
D O I
10.1016/S0040-4039(00)01168-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Aldehydes were converted into the corresponding nitriles by a homogeneous reaction with ammonia and aqueous hydrogen peroxide in the presence of copper salts or complexes under mild conditions. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:6749 / 6752
页数:4
相关论文
共 28 条
[1]  
[Anonymous], 1957, ORGANIC REACTIONS
[2]   Efficient one pot synthesis of Nitriles from Aldehydes in solid state using Peroxymonosulfate on Alumina [J].
Bose, DS ;
Narsaiah, AV .
TETRAHEDRON LETTERS, 1998, 39 (36) :6533-6534
[3]  
Brackman W., 1963, RECL TRAV CHIM PAY B, V82, P757
[4]  
CACCHI S, 1980, SYNTHESIS-STUTTGART, P243
[5]  
CAPDEVIELLE P, 1990, SYNTHESIS-STUTTGART, P451
[6]   Thionyl chloride-benzotriazole: An efficient system for transformation of aldoximes to nitriles [J].
Chaudhari, SS ;
Akamanchi, KG .
SYNTHETIC COMMUNICATIONS, 1999, 29 (10) :1741-1745
[7]   A new, mild, neutral and inexpensive method for conversion of aldoximes to nitriles using anhydrous ferric sulphate [J].
Desai, DG ;
Swami, SS ;
Mahale, GD .
SYNTHETIC COMMUNICATIONS, 2000, 30 (09) :1623-1625
[8]   REACTIONS OF ORGANIC PEROXIDES .12. AMINO-PEROXIDES FROM ACYCLIC CARBONYL COMPOUNDS [J].
HAWKINS, EGE .
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1969, (19) :2678-&
[9]   A new method for the generation of nitriles from aldoximes [J].
Jose, B ;
Sulatha, MS ;
Pillai, PM ;
Prathapan, S .
SYNTHETIC COMMUNICATIONS, 2000, 30 (08) :1509-1514
[10]  
KATRITZKY AR, 1989, SYNTHESIS-STUTTGART, P949