Catalysis of reactions of Si-H by titanocene and its derivatives

被引：66

作者：

Harrod, JF ^{[1
]}

机构：

[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada

来源：

COORDINATION CHEMISTRY REVIEWS | 2000年 / 206卷

基金：

加拿大自然科学与工程研究理事会;

关键词：

titanocene; organosilanes; hydrosilation; dehydrocoupling; redistribution; catalysis; enantioselection;

D O I：

10.1016/S0010-8545(00)00335-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review describes the remarkable ability of titanocene derivatives to catalyze reactions of Si-H compounds. These reactions involve addition of Si-H to unsaturated molecules, dehydrocoupling of Si-H with Si-H and with a variety of other E-H bonds, and redistribution of compounds containing the RO-Si-H bond system. The characterization of the many new titanocene complexes, which have been isolated as intermediates from these catalytic reactions, are also reviewed. (C) 2000 Elsevier Science S.A. All rights reserved.

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收藏

页码：493 / 531

页数：39

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